Allylchloro[1,3-bis(2,6-di-i-propylphenyl)-4,5-dihydroimidazol-2-ylidene]palladium(II) ≥99.95% (metals basis)

Supplier: ALADDIN SCIENTIFIC CORPORATION
Warning

Synonyms: Allyl(1,3-bis(2,6-diisopropylphenyl)imidazolidin-2-ylidene)chloropalladate(II), Umicore CX23, (SIPr)Pd(allyl)Cl, Allyl[1,3-bis(2,6-diisopropylphenyl)-2-imidazolidinylidene]chloropalladium(II), Allylchloro-[1,3-bis-(2,6-diisopropylphenyl)-2-imidazolidinylidene]palladium(II), Allylchloro[1,3-bis-(2,6-diisopropylphenyl)imidazol-2-idinylidene]palladium(II), Allyl[1,3-bis(2,6-diisopropylphenyl)-2-imidazolidinylidene]chloropalladium(II)

A284063-1G A284063-250MG
ALA284063-1GEA 1067.71 USD
ALA284063-1G ALA284063250MG
Allylchloro[1,3-bis(2,6-di-i-propylphenyl)-4,5-dihydroimidazol-2-ylidene]palladium(II) ≥99.95% (metals basis)
Allylchloro[1,3-bis(2,6-di-i-propylphenyl)-4,5-dihydroimidazol-2-ylidene]palladium(II)

Product classM-P, Homogeneous Catalysts, N-Heterocyclic Carbene Ligands, M-C, Allyl Ligands, SIPr, Bidentate LigandsReaction typeCross Coupling Reactions with Arenes, Amination, Buchwald-Hartwig Aminaton, Alpha Arylation, Suzuki-Miyaura Coupling ReactionChemical propertiesChemical formulaC30H43N2ClPdEmpirical formula(SIPr)Pd(allyl)ClMolecular weight573.56MetalPdTheoretical metal content19Physical statecrystallineColoryellowMetal purity99.95Applications & referencesα-Arylation of ketones.Reference: Org. Lett. 2002, 4, 4053 (DOI: 10.1021/ol026745m); Adv. Synth. Catal. 2012, 354, 377 (DOI: 10.1002/adsc.201100669)Intramolecular arylamination step in the synthetic approach of cryptocarya alkaloids.Reference: Synlett 2003, 12, 1871 (DOI: 10.1021/jo035834p)Suzuki-Miyaura coupling reaction.Reference: J. Org. Chem. 2004, 69, 3173Buchwald-Hartwig coupling reactions.Reference: J. Am. Chem. Soc. 2006, 128, 4101 (DOI: 10.1021/ja057704z)α-Heteroarylation of ketone enolates.Reference: J. Org. Chem. 2010, 75, 5316 (DOI: 10.1021/jo100623d)Palladium catalyzed anaerobic oxidation of secondary alcohols under mild reaction conditions.Reference: J. Org. Chem. 2011, 76, 1390. (DOI: 10.1021/jo102385u)Palladium catalyzed Buchwald-Hartwig- Reaction at room temperature.Reference: J. Am. Chem. Soc. 2006, 128, 4101. (DOI: 10.10217ja057704z)

Formula: C₃₀H₄₃ClN₂Pd
MW: 573.5600 g/mol
Melting Pt: 206-210 °C
Storage Temperature: Refrigerator
MDL Number: MFCD07782017
CAS Number: 478980-01-7

Order Now

Learn more

About VWR

Avantor is a vertically integrated, global supplier of discovery-to-delivery solutions for...

Learn more About VWR