Supplier:
ALADDIN SCIENTIFIC CORPORATION
Description:
Product classM-P, Homogeneous Catalysts, N-Heterocyclic Carbene Ligands, M-C, Allyl Ligands, SIPr, Bidentate LigandsReaction typeCross Coupling Reactions with Arenes, Amination, Buchwald-Hartwig Aminaton, Alpha Arylation, Suzuki-Miyaura Coupling ReactionChemical propertiesChemical formulaC30H43N2ClPdEmpirical formula(SIPr)Pd(allyl)ClMolecular weight573.56MetalPdTheoretical metal content19Physical statecrystallineColoryellowMetal purity99.95Applications & referencesα-Arylation of ketones.Reference: Org. Lett. 2002, 4, 4053 (DOI: 10.1021/ol026745m); Adv. Synth. Catal. 2012, 354, 377 (DOI: 10.1002/adsc.201100669)Intramolecular arylamination step in the synthetic approach of cryptocarya alkaloids.Reference: Synlett 2003, 12, 1871 (DOI: 10.1021/jo035834p)Suzuki-Miyaura coupling reaction.Reference: J. Org. Chem. 2004, 69, 3173Buchwald-Hartwig coupling reactions.Reference: J. Am. Chem. Soc. 2006, 128, 4101 (DOI: 10.1021/ja057704z)α-Heteroarylation of ketone enolates.Reference: J. Org. Chem. 2010, 75, 5316 (DOI: 10.1021/jo100623d)Palladium catalyzed anaerobic oxidation of secondary alcohols under mild reaction conditions.Reference: J. Org. Chem. 2011, 76, 1390. (DOI: 10.1021/jo102385u)Palladium catalyzed Buchwald-Hartwig- Reaction at room temperature.Reference: J. Am. Chem. Soc. 2006, 128, 4101. (DOI: 10.10217ja057704z)
